Union Engineering's CO2 generating plants (CBU) are based on the combustion of fuels such as diesel oil, heavy fuel oil, kerosene, natural gas, LPG, or LNG. Through combustion, scrubbing, absorption, stripping, adsorption, and separation technology, the CO2 generating plants meet the strictest CO2 quality requirements regardless of the fuel type.
Generating plants are based on the absorption of CO2 from flue gas into a monoethanolamine (MEA) based solution, which is heated by the steam-heated re-boiler to release the raw CO2 gas. To achieve the best combination of performance and equipment longevity, a 9% MEA /water solution is used. Under this condition, the optimal balance between CO2 load and avoidance of the corrosive effects of MEA is met.
Result-driven technology – NOxFlash and PUR-D
All our generating plants are based our amine technology, including NOxFlash and PUR-D. The NOxFlash technology is the result of innovation and research and has been proven in our installations since 2006. The NOxFlash technology:
The PUR-D technology is the final purification step, consisting of a distillation column, which enables separation/blow-off of non-condensable gasses, reducing the O2 content in the final product to max. 5 ppm (v/v) and obtaining a CO2 purity of min. 99.99% (v/v).
The electrical system of our Generating plants assures:
All plants are designed for high efficiency and reliability through components selected for 24/7 operation.
The plant is based on combustion of fuel in a MEA heater equipped with a burner. After the combustion, the flue gas will have a CO2 content of 10-14% v/v and will exit the MEA heater at a temperature of approximately 250°C.
The flue gas is directed to a flue gas scrubber, in which the gas is cooled and water condensed. Any SO2 present in the flue gas will be removed by means of a chemical reaction with sodium carbonate (soda ash). The soda ash is automatically added to the scrubbing water by means of pH control.
After cooling and scrubbing, the gas is led via an exhauster through an absorber, in which the gas flows counter-current to the MEA solution flow. By chemical reaction, the MEA solution absorbs the CO2 from the flue gas. The MEA solution containing the absorbed CO2 (referred to as rich MEA solution) is first pressurized and heated in a heat exchanger and then led to the NOxFlash column. Here most of the contaminants are removed from the rich MEA solution by flashing to the absorber pressure.
Further heating is added to the bottom of the NOxFlash column for further reduction of the contaminants in the MEA solution. This optimizes the process yield to the best possible CO2 product without any use of expensive chemicals (Pentair Union Engineering patent pending).
Afterwards, the rich MEA solution is pumped to a stripper, where the CO2 is released from the MEA solution by means of the combustion heat generated in the MEA heater. The CO2 depleted MEA solution (referred to as lean MEA solution) is recycled to the absorber. After exiting the top of the stripper, the CO2 rich gas is cooled in a gas cooler and washed in an after-scrubber for removal of potential MEA carry-over. The gas is then compressed in two stages to approx. 15-18 bar(g) by the CO2 compressor.
Prior to liquefaction, the gas is dried to a dew point of approx. -60°C (10 ppm v/v H2 O) in the dehydrator. Regeneration is done automatically by electrical heating and use of dry purge gas from the CO2 condenser. Traces (if any) of acetaldehyde are also removed in the dehydrator. The CO2 gas then passes through an activated carbon filter for removal of any odor substances.
To remove the last non-condensable gases, the CO2 gas first passes a reboiler in the purification system (type PUR-D). It is then condensed at a temperature of approx. -27°/-21°C in a CO2 condenser, where the non-condensed gases are purged off. Finally, the liquefied CO2 is led through the distillation column to an insulated storage tank.
A refrigeration unit, controlled by the CO2 pressure in the CO2 condenser, supplies the matching refrigeration capacity. The liquid CO2 is stored under a pressure of approx. 15-18 bar(g) and a corresponding temperature of approx. -27°/-21°C. During a non CO2 production period, the refrigeration unit is able to operate independently of the rest of the CO2 plant in order to maintain the correct CO2 storage tank temperature/pressure.
The CO2 produced has a purity higher than 99.99% (v/v) and fulfils quality standards as a food/beverage ingredient.
CO2 Generating Plant Standard Sizes (measured as liquid food-grade CO2 produced):
Other sizes available on request.
|Union Engineering CO2 Self-generating Plants - Combustion Based Unit - CBU|
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